There is a basic tutorial map to teach the basic mechanics of LoL. Like basic hero movement, the concept of buying items, leveling up, killing minions, towers, etc.
As for the real meat, understanding the map, knowing good item builds, which heroes will mess you up and in what way, most can be picked up by playing against bots, but ideally grab a partner and play.
OptimusTom is also a good resource.
Sullla has nice videos explaining specific champions and showing them throughout a game.
Riot Games provides decent info on how to play champion on their Champion Spotlight, although understanding masteries and runes will take a bit. But don't worry. Starting at level 1 they are happily locked away until you grasp the basics.
As for the real meat, understanding the map, knowing good item builds, which heroes will mess you up and in what way, most can be picked up by playing against bots, but ideally grab a partner and play.
OptimusTom is also a good resource.
Sullla has nice videos explaining specific champions and showing them throughout a game.
Riot Games provides decent info on how to play champion on their Champion Spotlight, although understanding masteries and runes will take a bit. But don't worry. Starting at level 1 they are happily locked away until you grasp the basics.
MP
Pitboss Demo - Darrell's Tropical Trolls
PBEM45G - Sareln
Pitboss Demo - Darrell's Tropical Trolls
PBEM45G - Sareln